Mesorat%20hashas for Chullin 168:7

ובכלי מתכות נמי לא אמרן אלא דלא שדי בהו ציביא אבל שדי בהו ציביא לית לן בה

Moreover, even if no spice roots were thrown into it we say [it is harmful] only if the water had not been boiled, but once it had boiled it can do no harm.

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