Reference for Berakhot 51:13

<big><strong>גמ׳</strong></big> ורמינהו מצותה עם הנץ החמה כדי שיסמוך גאולה לתפלה ונמצא מתפלל ביום

GEMARA I quote against the Mishnah : The obligation [of the Shema'] is at sunrise, so as to unite the Ge'ullah and the Tefillah, and consequently one says the Tefillah in the day-time!

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